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Chapter 22 — Chapter 22 — Hydrocarbons

3 topics + Exercise· CHEMISTRY — 10
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Topic 1 · pp. 116–118 · Free

Petroleum, Coal and Fractional Distillation

Source: Chemistry 10, Ch 22, pp. 116–118

📘Easy summary

Petroleum is a mixture of hydrocarbons separated by fractional distillation based on boiling point ranges: crude oil heated to ~400 °C, vapours rise in a fractionating tower, cooling upward; fractions condense at different heights: refinery gas/LPG (<40 °C), petrol/gasoline (40–75), naphtha, kerosene (jet fuel), diesel, fuel oil (ships, power stations generating electricity), lubricating oil, wax, bitumen/asphalt (road surfacing — not a fuel). As boiling point increases: molecular size, viscosity, density increase; volatility, flammability, ease of ignition decrease; colour darker. Coal destructive distillation gives coke, coal gas, coal tar (benzene, toluene, phenol, naphthalene) and ammoniacal liquor.

⭐Key points

  • Asphalt not fuel.

🔬Diagram

Fractionating columnCrude heatedVapours riseCooling with heightFractions condensed

🌿Real-life example

CNG = natural gas (methane).

💡Exam tip

  • Properties vs b.p.

✅Quick check

1. Fractional distillation based on:

2. Power plants use:

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