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Chapter 17 — Chapter 17 — Reaction Kinetics

4 topics + Exercise· CHEMISTRY — 10
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Topic 1 · pp. 55–57 · Free

Collision Theory

Source: Chemistry 10, Ch 17, pp. 55–57

📘Easy summary

Reactions occur when particles collide. Collision frequency: number of collisions per unit volume per unit time. Only successful (effective) collisions — with energy ≥ activation energy (Eₐ, minimum energy needed) and proper orientation — form products. Reactants climb the energy hill to an activated complex (transition state), which then breaks down into products. Rate is fastest at the start because reactant concentration is highest; it slows as reactants are used up (reactants ↓, products ↑).

⭐Key points

  • Energy comes from KE of moving molecules (heat).

🔬Diagram

Reaction pathReactantsCollide with E ≥ EₐActivated complexProducts

🌿Real-life example

Mixture of H₂ and O₂ needs a spark.

💡Exam tip

  • Define Eₐ precisely.

✅Quick check

1. Collisions per unit volume:

2. E > Eₐ reaction is:

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